Monday, April 17, 2017

New Battery Coating Could Improve Smart Phones and Electric Vehicles

UCR Today


Discovery by UC Riverside researchers helps unravel more than 40-year mystery and could greatly improve battery performance in electronic devices and electric vehicles
By Sean Nealon on April 17, 2017
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Illustrations of the design principles of using methyl viologen to form a stable coating to allow the stable cycling of lithium metal.

RIVERSIDE, Calif. (www.ucr.edu) — High performing lithium-ion batteries are a key component of laptops, smart phones, and electric vehicles. Currently, the anodes, or negative charged side of lithium ion batteries, are generally made with graphite or other carbon-based materials.
But, the performance of carbon based materials is limited because of the weight and energy density, which is the amount of energy that can be stored in a given space. As a result, a lot of research is focused on lithium-metal anodes.
The success of lithium metal anodes will enable many battery technologies, including lithium metal and lithium air, which can potentially increase the capacity of today’s best lithium-ion batteries five to 10 times. That would mean five to 10 times more range for electric vehicles and smartphone batteries lasting five to 10 times more time. Lithium metal anodes are also lighter and less expensive.
The problem with lithium ion batteries made with metal is that during charge cycles they uncontrollably grow dendrites, which are microscopic fibers that look like tree sprouts. The dendrites degrade the performance of the battery and also present a safety issue because they can short circuit the battery and in some cases catch fire.
A team of researchers at the University of California, Riverside has made a significant advancement in solving the more than 40-year-old dendrite problem. Their findings were just published in the journal Chemistry of Materials.
The team discovered that by coating the battery with an organic compound called methyl viologen they are able to stabilize battery performance, eliminate dendrite growth and ...

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